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趙桓(宋(song)(song)(song)(song)欽宗(zong)(zong))即(ji)位后，升李(li)(li)綱(gang)(gang)(gang)為(wei)尚書(shu)右丞，就(jiu)任(ren)(ren)親征行營(ying)使，負(fu)責開(kai)封(feng)的防(fang)御(yu)(yu)。李(li)(li)綱(gang)(gang)(gang)率(lv)領開(kai)封(feng)軍民及時(shi)完成防(fang)御(yu)(yu)部署，親自登城(cheng)督戰(zhan)，擊(ji)退金(jin)(jin)(jin)(jin)兵。金(jin)(jin)(jin)(jin)帥(shuai)完顏(yan)宗(zong)(zong)望(wang)見開(kai)封(feng)難以(yi)強攻(gong)，轉而(er)施(shi)行誘降之(zhi)計，宋(song)(song)(song)(song)廷彌(mi)漫了屈辱投降的氣氛。李(li)(li)綱(gang)(gang)(gang)因堅(jian)決反對向金(jin)(jin)(jin)(jin)割地求和，被(bei)宋(song)(song)(song)(song)欽宗(zong)(zong)罷官。由于開(kai)封(feng)軍民憤(fen)怒示(shi)威，迫(po)使宋(song)(song)(song)(song)欽宗(zong)(zong)收回成命，李(li)(li)綱(gang)(gang)(gang)才(cai)又被(bei)起用。完顏(yan)宗(zong)(zong)望(wang)因無力攻(gong)破開(kai)封(feng)，在宋(song)(song)(song)(song)廷答應(ying)割讓河北(bei)三鎮之(zhi)后，遂于靖(jing)康元(yuan)(yuan)年(nian)(nian)(nian)(1126年(nian)(nian)(nian))二月撤兵。開(kai)封(feng)守(shou)衛戰(zhan)在李(li)(li)綱(gang)(gang)(gang)組(zu)織下獲得勝利(li)。金(jin)(jin)(jin)(jin)兵撤離之(zhi)后，李(li)(li)綱(gang)(gang)(gang)即(ji)遭到宋(song)(song)(song)(song)廷投降派的排斥和誣陷。靖(jing)康元(yuan)(yuan)年(nian)(nian)(nian)(1126年(nian)(nian)(nian))五(wu)月，宋(song)(song)(song)(song)廷強令(ling)李(li)(li)綱(gang)(gang)(gang)出任(ren)(ren)河東、河北(bei)宣撫(fu)使，驅(qu)趕他出朝(chao)。李(li)(li)綱(gang)(gang)(gang)就(jiu)任(ren)(ren)后，宋(song)(song)(song)(song)廷又事(shi)事(shi)加以(yi)限制，使宣撫(fu)使徒(tu)具空名，無節制軍隊(dui)之(zhi)權。李(li)(li)綱(gang)(gang)(gang)被(bei)迫(po)于靖(jing)康元(yuan)(yuan)年(nian)(nian)(nian)(1126年(nian)(nian)(nian))九月辭職，旋又被(bei)加上“專主戰(zhan)議，喪師費財”的罪名，先(xian)(xian)責建昌軍(今(jin)(jin)江西(xi)南(nan)城(cheng))安置，再(zai)謫夔州(zhou)(今(jin)(jin)重慶(qing)奉節白帝城(cheng))。李(li)(li)綱(gang)(gang)(gang)被(bei)貶不久，金(jin)(jin)(jin)(jin)兵再(zai)次兩(liang)路南(nan)下圍攻(gong)開(kai)封(feng)。宋(song)(song)(song)(song)欽宗(zong)(zong)在被(bei)俘(fu)前夕(xi)又想起用李(li)(li)綱(gang)(gang)(gang)，任(ren)(ren)命他為(wei)資政(zheng)殿大(da)學士(shi)、領開(kai)封(feng)府事(shi)，但(dan)已無濟(ji)于事(shi)。南(nan)宋(song)(song)(song)(song)建立后，他主張(zhang)堅(jian)決抗金(jin)(jin)(jin)(jin)及反對投降活動，卻(que)為(wei)宋(song)(song)(song)(song)高(gao)宗(zong)(zong)及汪伯彥、黃潛善所不容(rong)。因此，他們又設法驅(qu)逐李(li)(li)綱(gang)(gang)(gang)。首(shou)先(xian)(xian)，調(diao)李(li)(li)綱(gang)(gang)(gang)任(ren)(ren)尚書(shu)左仆射兼門下侍(shi)郎(左相)，另委(wei)黃潛善接任(ren)(ren)右仆射兼中書(shu)侍(shi)郎，以(yi)牽制李(li)(li)綱(gang)(gang)(gang)。接著，又罷免張(zhang)所、傅(fu)亮，撤銷(xiao)河北(bei)招撫(fu)司(si)及河東經制司(si)，蓄意破壞李(li)(li)綱(gang)(gang)(gang)的抗金(jin)(jin)(jin)(jin)部署，迫(po)使李(li)(li)綱(gang)(gang)(gang)辭職。李(li)(li)綱(gang)(gang)(gang)主政(zheng)僅七十(shi)五(wu)天，建炎元(yuan)(yuan)年(nian)(nian)(nian)(1127年(nian)(nian)(nian))八月十(shi)八日便(bian)遭罷相，為(wei)觀文殿大(da)學士(shi)，提舉杭州(zhou)洞霄宮。一生為(wei)國(guo)，卻(que)不得愿。