什么是充電電池
充(chong)電(dian)(dian)(dian)(dian)(dian)電(dian)(dian)(dian)(dian)(dian)池(chi),是充(chong)電(dian)(dian)(dian)(dian)(dian)次數有限的(de)(de)可(ke)充(chong)電(dian)(dian)(dian)(dian)(dian)的(de)(de)電(dian)(dian)(dian)(dian)(dian)池(chi),配合(he)(he)充(chong)電(dian)(dian)(dian)(dian)(dian)器使用。市場上一般賣5號、7號,但是也有1號。充(chong)電(dian)(dian)(dian)(dian)(dian)電(dian)(dian)(dian)(dian)(dian)池(chi)的(de)(de)好處是經濟、環保、電(dian)(dian)(dian)(dian)(dian)量足、適合(he)(he)大功(gong)率、長時間使用的(de)(de)電(dian)(dian)(dian)(dian)(dian)器(如隨身(shen)聽、電(dian)(dian)(dian)(dian)(dian)動玩具等)。充(chong)電(dian)(dian)(dian)(dian)(dian)電(dian)(dian)(dian)(dian)(dian)池(chi)的(de)(de)電(dian)(dian)(dian)(dian)(dian)壓比型(xing)號相同(tong)的(de)(de)一次性電(dian)(dian)(dian)(dian)(dian)池(chi)低,AA電(dian)(dian)(dian)(dian)(dian)池(chi)(5號充(chong)電(dian)(dian)(dian)(dian)(dian))是1.2伏(fu),9V充(chong)電(dian)(dian)(dian)(dian)(dian)電(dian)(dian)(dian)(dian)(dian)池(chi)實際上是 8.4伏(fu)。現在(zai)一般充(chong)電(dian)(dian)(dian)(dian)(dian)次數能在(zai)1000次左右。目前只有五種:鎳鎘、鎳氫、鋰離(li)子(zi)、鉛(qian)蓄、鐵鋰。
種類
鎳鎘電池(Ni-Cd)
電(dian)壓:1.2V 充(chong)電(dian)電(dian)池 使用壽(shou)命為:500次 放電(dian)溫(wen)度(du)為:-20度(du)~60度(du) 充(chong)電(dian)溫(wen)度(du)為:0度(du)~45度(du)
鎳氫電池(Ni-MH)
電(dian)(dian)壓:1.2V 使用壽命為:1000次(ci) 放電(dian)(dian)溫(wen)度為:-10度~45度 充電(dian)(dian)溫(wen)度為:10度~45度
備注:目前國產5號電池(chi)最(zui)高容(rong)量是(shi)2500mAh左(zuo)右。
鋰離子電池(Li-lon)
電(dian)(dian)壓(ya):3.6V 使用(yong)壽命為:500次 放電(dian)(dian)溫(wen)度(du)(du)為:-20度(du)(du)~60度(du)(du) 充電(dian)(dian)溫(wen)度(du)(du)為:0度(du)(du)~45度(du)(du)
備注:重量比(bi)鎳氫(qing)電池輕30%~40%,容量高出鎳氫(qing)電池60%以(yi)上。但(dan)是不耐過(guo)充,如果過(guo)充會造(zao)成溫度(du)過(guo)高而(er)破壞結構=>爆炸。
鋰聚合物電池(Li-polymer)
電(dian)(dian)(dian)壓:3.7V 使用壽命為:500次(ci) 充(chong)電(dian)(dian)(dian)電(dian)(dian)(dian)池 放電(dian)(dian)(dian)溫度(du)為:-20度(du)~60度(du) 充(chong)電(dian)(dian)(dian)溫度(du)為:0度(du)~45度(du)
備注(zhu):鋰電(dian)(dian)(dian)的改良型(xing),沒(mei)有(you)電(dian)(dian)(dian)池(chi)液,而(er)改用聚合物電(dian)(dian)(dian)解質,可以做成各(ge)種形狀,比鋰電(dian)(dian)(dian)池(chi)穩定。
鉛酸電池(Sealed)
電(dian)壓:2V 使(shi)用壽(shou)命(ming)為(wei)(wei):200~300次 放電(dian)溫(wen)度(du)(du)為(wei)(wei):0度(du)(du)~45度(du)(du) 充電(dian)溫(wen)度(du)(du)為(wei)(wei):0度(du)(du)~45度(du)(du)
備注:就是一般車用電瓶(它是以6個2V串聯(lian)成12V的(de)),免加水(shui)的(de)電池使用壽命長達(da)10年(nian),但體積和容量(liang)是最大的(de)。
特征
鎳鎘: 有(you)記憶(yi)效應 容(rong)量(liang)小
鎳(nie)氫: 記憶效應(ying)小 容量大
鋰(li)離子: 無記憶效應 身薄(bo) 容量(liang)(liang)大,因電(dian)(dian)極材料不同,電(dian)(dian)動(dong)勢為3.6V、3.7V兩種(zhong)。鋰(li)電(dian)(dian)池的(de)性能是現(xian)有各(ge)類電(dian)(dian)池中(zhong)最好的(de)一(yi)種(zhong),體(ti)積小、重量(liang)(liang)輕、容量(liang)(liang)大。廣(guang)泛用于數碼(ma)相機、筆記本電(dian)(dian)腦、移動(dong)電(dian)(dian)話(hua)等電(dian)(dian)子產(chan)品中(zhong)。
鉛蓄(xu):電動勢約為(wei)2V,鉛蓄(xu)電池可以(yi)反復充(chong)電使用(yong),電解液是硫酸溶液,內(nei)阻(zu)很小,廣泛(fan)用(yong)于(yu)汽車、摩托車中。
鐵鋰:電(dian)力更(geng)足(zu),更(geng)安(an)全,也更(geng)輕(qing),未(wei)來電(dian)動車的(de)主要(yao)發(fa)展方向。一般,同(tong)種類型的(de)充(chong)電(dian)電(dian)池(chi),容量越大(da),體積越大(da),重量也較大(da)。
名詞解釋
充電(dian)率(lv)(C-rate)
C是(shi)Capacity的(de)第一個字(zi)母,用來表(biao)示電(dian)池(chi)充放電(dian)時電(dian)流(liu)的(de)大小(xiao)數值。例如(ru):充電(dian)電(dian)池(chi)的(de)額定容量(liang)為1100mAh時,即(ji)表(biao)示以(yi)(yi)1100mAh(1C)放電(dian)時間可(ke)持續(xu)(xu)1小(xiao)時,如(ru)以(yi)(yi)200mA(0.2C)放電(dian)時間可(ke)持續(xu)(xu)5小(xiao)時,充電(dian)也可(ke)按此對照(zhao)計(ji)算(suan)。
終止(zhi)電壓(Cut-off discharge voltage)
指電(dian)池(chi)放(fang)(fang)(fang)電(dian)時(shi),電(dian)壓(ya)下降到電(dian)池(chi)不(bu)(bu)宜再繼續放(fang)(fang)(fang)電(dian)的(de)(de)(de)(de)(de)最低工作電(dian)壓(ya)值。根據不(bu)(bu)同的(de)(de)(de)(de)(de)電(dian)池(chi)類型及不(bu)(bu)同的(de)(de)(de)(de)(de)放(fang)(fang)(fang)電(dian)條件(jian),電(dian)池(chi)放(fang)(fang)(fang)電(dian)的(de)(de)(de)(de)(de)終(zhong)止電(dian)壓(ya)也不(bu)(bu)相(xiang)同。規定(ding)終(zhong)止電(dian)壓(ya)放(fang)(fang)(fang)一般(ban)(ban)都要隨放(fang)(fang)(fang)電(dian)電(dian)流(liu)的(de)(de)(de)(de)(de)增大而減(jian)少。以1.2V、800mah鎳(nie)氫電(dian)池(chi)為例,采取40ma(20小時(shi)率)的(de)(de)(de)(de)(de)放(fang)(fang)(fang)電(dian)電(dian)流(liu)它(ta)的(de)(de)(de)(de)(de)放(fang)(fang)(fang)電(dian)終(zhong)止電(dian)壓(ya)一般(ban)(ban)設定(ding)在(zai)1.15v;采取80ma(10小時(shi)率)的(de)(de)(de)(de)(de)放(fang)(fang)(fang)電(dian)電(dian)流(liu)則它(ta)的(de)(de)(de)(de)(de)放(fang)(fang)(fang)電(dian)終(zhong)止電(dian)壓(ya)就要設定(ding)在(zai)1.10v了。
開路電壓(Open circuit voltage OCV)
電池(chi)不(bu)放(fang)電時,電池(chi)兩(liang)極之(zhi)間的(de)(de)電位差被(bei)稱為開路(lu)電壓(ya)。電池(chi)的(de)(de)開路(lu)電壓(ya),會(hui)依電池(chi)正(zheng)(zheng)、負極與(yu)電解液的(de)(de)材料(liao)而異,如果電池(chi)正(zheng)(zheng)、負極的(de)(de)材料(liao)完全一(yi)樣,那么不(bu)管(guan)電池(chi)的(de)(de)體積(ji)有多大(da),幾(ji)何結構(gou)如何變(bian)化,起開路(lu)電壓(ya)都一(yi)樣的(de)(de)。
放電深(shen)度(du)(Depth of discharge DOD)
在電(dian)池(chi)(chi)(chi)使用過程(cheng)中,電(dian)池(chi)(chi)(chi)放(fang)出的(de)容量占其額定(ding)容量的(de)百分比,稱為放(fang)電(dian)深度。放(fang)電(dian)深度的(de)高低和二次(ci)電(dian)池(chi)(chi)(chi)的(de)充(chong)電(dian)壽命(ming)有(you)很(hen)深的(de)關系,當二次(ci)電(dian)池(chi)(chi)(chi)的(de)放(fang)電(dian)深度越深,其充(chong)電(dian)壽命(ming)就(jiu)越短,因此在使用時(shi)應盡量避免(mian)深度放(fang)電(dian)。
過放電(dian)(Over discharge)
電(dian)(dian)(dian)池(chi)若是在(zai)放(fang)電(dian)(dian)(dian)過程中,超過電(dian)(dian)(dian)池(chi)放(fang)電(dian)(dian)(dian)的終(zhong)止電(dian)(dian)(dian)壓(ya)值(zhi),還繼(ji)續放(fang)電(dian)(dian)(dian)時就(jiu)可能會(hui)造成電(dian)(dian)(dian)池(chi)內壓(ya)升(sheng)高,正、負極活性物質的可逆性遭到(dao)損壞,使(shi)電(dian)(dian)(dian)池(chi)的容(rong)量產生明顯減少(shao)。
過度(du)充電 (Over charge)
在充(chong)(chong)電(dian)(dian)過(guo)程中電(dian)(dian)池(chi)的(de)電(dian)(dian)壓會(hui)(hui)隨著儲存(cun)(cun)電(dian)(dian)量的(de)增(zeng)加而逐(zhu)漸上升(sheng),當(dang)電(dian)(dian)池(chi)儲存(cun)(cun)的(de)電(dian)(dian)量達到飽和電(dian)(dian)極(ji)材料無法繼續充(chong)(chong)電(dian)(dian)時,若繼續充(chong)(chong)電(dian)(dian)則電(dian)(dian)解(jie)液會(hui)(hui)起電(dian)(dian)解(jie),并且在陽極(ji)產(chan)生氧氣,在陰極(ji)產(chan)生氫(qing)氣,如(ru)此(ci)會(hui)(hui)在密封的(de)電(dian)(dian)池(chi)內(nei)部造成(cheng)內(nei)部壓力上升(sheng),會(hui)(hui)對電(dian)(dian)池(chi)內(nei)部結構造成(cheng)破壞.像這種現象(xiang)稱之為過(guo)度(du)充(chong)(chong)電(dian)(dian).
為了(le)避(bi)免過度(du)(du)充(chong)(chong)電(dian)電(dian)池(chi)(chi)遭毀損(sun),通常(chang)將(jiang)(jiang)陰極之容(rong)量制作得(de)比陽(yang)極容(rong)量大(da),如此當過度(du)(du)充(chong)(chong)電(dian)時陽(yang)極會(hui)(hui)先達(da)到(dao)飽和并產(chan)生(sheng)氧(yang)(yang)氣,而陰極卻未(wei)飽和而不會(hui)(hui)產(chan)生(sheng)氫氣,陽(yang)極產(chan)生(sheng)的(de)(de)氧(yang)(yang)氣擴散(san)到(dao)陰極之后會(hui)(hui)與充(chong)(chong)電(dian)產(chan)生(sheng)的(de)(de)金屬(shu)鎘(ge)起(qi)化(hua)學(xue)反(fan)(fan)應吸收(shou)掉氧(yang)(yang)氣,且此反(fan)(fan)應的(de)(de)速度(du)(du)與金屬(shu)鎘(ge)產(chan)生(sheng)的(de)(de)速度(du)(du)平衡(heng),因此可以(yi)有(you)效地(di)避(bi)免電(dian)池(chi)(chi)的(de)(de)壓(ya)力(li)上(shang)升.但是(shi)若(ruo)充(chong)(chong)電(dian)電(dian)流過大(da)(使用快(kuai)充(chong)(chong)時)就會(hui)(hui)失去平衡(heng),電(dian)池(chi)(chi)的(de)(de)內壓(ya)過大(da)會(hui)(hui)將(jiang)(jiang)電(dian)池(chi)(chi)的(de)(de)安全閥(fa)推開,氫氣和氧(yang)(yang)氣會(hui)(hui)泄(xie)漏(lou)到(dao)電(dian)池(chi)(chi)外部(bu),直(zhi)到(dao)壓(ya)力(li)降低安全閥(fa)關閉電(dian)池(chi)(chi)才又(you)再密封起(qi)來(lai).但是(shi)氣體的(de)(de)泄(xie)漏(lou)已使得(de)內部(bu)化(hua)學(xue)材料(liao)減少,造成(cheng)電(dian)池(chi)(chi)壽命的(de)(de)縮(suo)短(duan)。
能量密度(Energy density)
電(dian)池(chi)(chi)的(de)平均單位(wei)體積(ji)或質量所釋放出的(de)電(dian)能。一般(ban)在(zai)相(xiang)同體積(ji)下,鋰離子電(dian)池(chi)(chi)的(de)能量密度(du)是鎳(nie)鎘(ge)電(dian)池(chi)(chi)的(de)2.5倍,是鎳(nie)氫電(dian)池(chi)(chi)的(de)1.8倍,因(yin)此在(zai)電(dian)池(chi)(chi)容(rong)量相(xiang)等的(de)情況(kuang)下,鋰離子電(dian)池(chi)(chi)就會比鎳(nie)鎘(ge)、鎳(nie)氫電(dian)池(chi)(chi)的(de)體積(ji)更小(xiao),重(zhong)量更輕。
自我(wo)放電(Self discharge)
電池不管(guan)在有無被使用的(de)狀態下,由于各(ge)種(zhong)原因,都會引起其電量損(sun)失(shi)的(de)現象。若是(shi)以一(yi)個月(yue)為單位來計算的(de)話,鋰離子電池自我放(fang)電約是(shi)1%-2%、鎳(nie)氫電池自我放(fang)電約3%-5%。
充電(dian)循(xun)環壽命(ming)(Cycle life)
充電電池(chi)在反復充放電使用下(xia),電池(chi)容量回逐(zhu)漸下(xia)降到初期容量的60%-80%。
記憶效應(ying)(Memory effect)
在電池充放電過(guo)程中,會(hui)在電池極板上產生許多(duo)小氣(qi)泡(pao),時間一久,這些氣(qi)泡(pao)會(hui)減少電池極板的面積,也間接(jie)影(ying)響電池的容量。
中國電池發展前景
中(zhong)國(guo)(guo)(guo)電(dian)池(chi)出(chu)口(kou)有大(da)(da)幅增長,但同時歐盟綠(lv)色壁壘、中(zhong)國(guo)(guo)(guo)電(dian)池(chi)出(chu)口(kou)退稅制度取消、原(yuan)材料上漲(zhang)、國(guo)(guo)(guo)外企業(ye)壟(long)斷高(gao)端市場等(deng)問題制約(yue)著(zhu)中(zhong)國(guo)(guo)(guo)電(dian)池(chi)行(xing)業(ye)發展。中(zhong)國(guo)(guo)(guo)已成為全球最大(da)(da)的電(dian)池(chi)生(sheng)產國(guo)(guo)(guo)和最大(da)(da)的電(dian)池(chi)消耗國(guo)(guo)(guo),但產品更新換(huan)代(dai)不(bu)及(ji)時,生(sheng)產自動化、機械化程度不(bu)高(gao),為了適應世(shi)界(jie)電(dian)池(chi)業(ye)發展的趨勢,中(zhong)國(guo)(guo)(guo)必(bi)須致力于太陽能電(dian)池(chi)和燃料電(dian)池(chi)等(deng)新型(xing)電(dian)池(chi)的研發,大(da)(da)力發展高(gao)新技(ji)術的電(dian)池(chi)產品。
電池業是中國的重點產業之一,有著良好發展前景。二十一世紀的電池具有大容量、高功率、長壽命、無污染、安全可靠輕便的特點,是高科技、高產出、高利潤、高創匯產品。隨著信息時代的到來,資訊產業蓬勃發展,在邁入電子、資訊、通訊的“3C”時代后,電子產品朝著“短、小、輕、薄”的趨勢發展,作為電子產品不可或缺的電池,其重要性也越來越顯著。